Expertise in the Physical
Characterisation of Materials
MCA Services
Unit 1A Long Barn, North End, Meldreth, Cambridgeshire SG8 6NT UK
01763 262333
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BET Surface Area by Nitrogen and Krypton Adsorption
The surface area of a material will often profoundly effect its behaviour and performance, whatever its application, and will commonly be a
critical parameter to consider when preparing or procuring a material. For example, surface area can be used to directly determine factors
such as reactivity, adsorption capacity, dissolution rate, electrochemical performance and burning / sintering ability. Knowledge and control
of surface area is often crucial at all stages of formulation, manufacture and ongoing QC processes.
Surface area, also termed Specific Surface Area (SSA), is most commonly measured by the BET (Brunauer-Emmett-Teller) method through
the gas adsorption technique. For the majority of samples nitrogen adsorption is used, but for very low surface area materials a krypton
adsorption option is also available.
Key Information
•
Surface area is a critical parameter for formulation, production and
performance.
•
Surface area often affects material performance
•
Surface area is often critical to material selection
•
BET Surface Area by Nitrogen adsorption
•
BET Surface area by Krypton adsorption for low area materials
•
Comprehensive degassing options available to suit specific requirements
•
Volumetric technique using state-of-the-art Micromeritics TriStar II 3020
•
Single point and multipoint measurement options available
•
Flowing gas method available where required
•
Argon adsorption option available
•
Carbon dioxide and oxygen adsorption options available
Sample
degassing
and
drying
immediately
prior
to
analysis
is
critical
to
ensure
that
samples
are
clean
and
dry.
This
is
undertaken
by
MCA
and
a
range
of
options
are
available,
including
vacuum
and
flowing
gas
techniques
at
temperatures
from
ambient
to
400
°C
are
available
to
ensure that samples are fully degassed without thermal degradation.
Nitrogen
adsorption
is
applicable
to
the
majority
of
sample
types.
However,
as
surface
area
becomes
particularly
low
nitrogen
fails
to
provide
accurate
data
from
which
to
calculate
surface
area.
In
such
cases
a
krypton
adsorption
option
is
also
offered
which
is
capable
of
measuring the geometric area of essentially non-porous materials.
Analyses
are
usually
undertaken
using
the
most
recent
Micromeritics
TriStar
3020
instrument,
offering
a
multipoint
volumetric
technique.
However,
a
flowing
gas
technique
and
single
point
measurement
options
are
also
available
which
provide
options
to
match
historical
methods and data.